General
Name, Symbol, NumberPolonium, Po, 84
Series Metalloids
Group, Period, Block6 (VIA), 6 , p
Density, Hardness 9196 kg/m3, no data
Appearance silvery
Atomic Properties
Atomic weight [209] amu
Atomic radius (calc.) 190 (135)pm
Covalent radius no data
van der Waals radius no data
Electron configuration [Xe]44f14 5d10 6s2 6p4
e- 's per energy level2, 8, 18, 32, 18, 6
Oxidation states (Oxide) 4, 2 (amphoteric)
Crystal structure Monoclinic
Physical Properties
State of matter Solid (nonmagnetic)
Melting point 527 K (489 F)
Boiling point 1235 K (1764 F)
Molar volume 22.97 ×1010-3 m3/mol
Heat of vaporization no data
Heat of fusion 60.1 kJ/mol
Vapor pressure 0.0176 Pa at 527 K
Speed of sound no data
Miscellaneous
Electronegativity 2.0 (Pauling scale)
Specific heat capacity no data
Electrical conductivity 2.19 106/m ohm
Thermal conductivity 20 W/(m*K)
1st ionization potential 812.1 kJ/mol
Most Stable Isotopes
isoNAhalf-life DMDE MeVDP
208Po{syn.}2.898 yAlpha
Epsilon
5.215
1.401
204Pb
208Bi
209Po{syn.}103 yAlpha
Epsilon
4.979
1.893
205Pb
209Bi
210Po{syn.}138.376 dAlpha5.407206Pb
SI units & STP are used except where noted.
Polonium is a chemical element in the periodic table that has the symbol Po and atomic number 84. A rare radioactive metalloid, polonium is chemically similar to tellurium and bismuth and occurs in uranium ores. Polonium had been studied for possible use in heating spacecraft.

Table of contents
1 Notable Characteristics
2 Applications
3 History
4 Occurrence
5 Isotopes
6 Precautions
7 External Links

Notable Characteristics

This radioactive substance dissolves readily in dilute acids, but is only slightly soluble in alkalis. It is closely related chemically to bismuth and tellurium.

Polonium-210 is a volatile metal with 50% being vaporized in air after 45 hours at 328 K. This isotope is an alpha emitter that has a half-life of 138.39 days. A milligram of this metalloid emits as many alpha particles as 5 grams of radium.

A great deal of energy is released by its decay with a half a gram quickly reaching a temperature above 750 K. A few curies of polonium emit a blue glow which is caused by excitation of surrounding air.

Applications

When it is mixed or alloyed with beryllium, polonium can be a neutron source. Other uses;
  • This element has also been used in devices that eliminate static charges in textile mills and other places. However beta sources are more commonly used and are less dangerous.
  • Polonium is used on brushes that remove accumulated dust from photographic films. The polonium in these brushes is sealed and controlled thus minimizing radiation hazards.
Since nearly all alpha radiation can be easily stopped by ordinary containers and upon hitting its surface releases its energy, polonium has been proposed as a lightweight heat source to power thermoelectric cells in artificial satellites.

History

Also called Radium F, polonium was discovered by
Marie Curie and Pierre Curie in 1898 and was later named after Marie's home country of Poland.

This element was the first one discovered by the Curies while they were investigating the cause of pitchblend radioactivity. The electroscope showed it separating with bismuth.

Occurrence

A very rare element in nature, polonium is found in uranium ores at about 100 micrograms per ton. Its natural abundance is approximately 0.2% of radium's.

In 1934 an experiment showed that when natural bismuth (Bi-209) is bombarded with neutrons, Bi-210, which is the parent of polonium, was created. Polonium may now be made in milligram amounts in this procedure which uses high neutron fluxes found in nuclear reactors.

Isotopes

Polonium has more isotopes than any other element, all of which are radioactive. There are 25 known isotopes of polonium with atomic masses that range from 194 to 218. Polonium-210 is the most widely available. Po-209 (half-life 103 years) and Po-208 (half-life 2.9 years) can be made through the alpha, proton, or deuteron bombardment of lead or bismuth in a cyclotron. However these isotopes are expensive to produce.

Precautions

Polonium is a highly radioactive and toxic element and is dangerous to handle. Even
milligram or microgram amounts, handling polonium-210 is very dangerous and requires special equipment used with strict procedures. Direct damage occurs from energy absorption into tissues from alpha particles.

The maximum allowable body burden for ingested polonium is only 0.03 microcuries, which is equivalent to a particle weighing only 6.8 x 10-12 gram. Weight for weight polonium is approximately 2.5 x 1011 times as toxic as hydrocyanic acid. The maximum permissible concentration for airborne soluble polonium compounds is about 2 x 10-11 microcuries/cm3.

External Links