Cetane or CN is to diesel fuel what octane is to gasoline. It is a measure of the fuel's combustion quality.

Cetane is actually an alkane, its real name is 1-hexadecane. It is written as C16H34, or a chain of 16 carbon atoms with 34 hydrogen atoms attached. All HC chains are also referred to as paraffins. Cetane is a hydrocarbon molecule that ignites very easily under compression, so it was assigned a rating of 100. All the hydrocarbons in diesel fuel are indexed to cetane as to how well they ignite under compression.

So, the cetane number measures how quickly the fuel starts to burn (auto-ignites) under diesel engine conditions. Since there are hundreds of components in diesel fuel, with each having a different cetane quality, the overall cetane number of the diesel is the average cetane quality of all the components.

A fuel with a high cetane number starts to burn shortly after it is injected into the cylinder; it has a short ignition delay period. Conversely, a fuel with a low cetane number resists auto-ignition and has a longer ignition delay period.

Cetane Number is a measure of how readily the fuel . A fuel with a high cetane number starts to burn shortly after it is injected into the cylinder; it has a short ignition delay period. Conversely, a fuel with a low cetane number resists auto-ignition and has a longer ignition delay period.

There is very little actual cetane in diesel fuel. Diesel engines run just fine with a CN between 45 to 50. There is no performance or emission advantage to keep raising the CN past 50. After that point the fuel's performance hits a plateau.

Diesel at the pump can be found in two CN ranges: 40-46 for regular diesel, and 45-50 for premium. Premium diesel has additives to improve CN & lubricity, detergents to clean the fuel injectors and minimize carbon deposits, water dispersant, and other additives depending on geographical and seasonal needs.